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A novel cryogenic insulation system of hollow glass microspheres and self-evaporation vapor-cooled shield

Jianpeng ZHENG, Liubiao CHEN, Ping WANG, Jingjie ZHANG, Junjie WANG, Yuan ZHOU

《能源前沿（英文）》 2020年 第14卷 第3期   页码 570-577 doi: 10.1007/s11708-019-0642-y

摘要： Liquid hydrogen (LH ) attracts widespread attention because of its highest energy storage density. However, evaporation loss is a serious problem in LH storage due to the low boiling point (20 K). Efficient insulation technology is an important issue in the study of LH storage. Hollow glass microspheres (HGMs) is a potential promising thermal insulation material because of its low apparent thermal conductivity, fast installation (Compared with multi-layer insulation, it can be injected in a short time.), and easy maintenance. A novel cryogenic insulation system consisting of HGMs and a self-evaporating vapor-cooled shield (VCS) is proposed for storage of LH . A thermodynamic model has been established to analyze the coupled heat transfer characteristics of HGMs and VCS in the composite insulation system. The results show that the combination of HGMs and VCS can effectively reduce heat flux into the LH tank. With the increase of VCS number from 1 to 3, the minimum heat flux through HGMs decreases by 57.36%, 65.29%, and 68.21%, respectively. Another significant advantage of HGMs is that their thermal insulation properties are not sensitive to ambient vacuum change. When ambient vacuum rises from 10 Pa to 1 Pa, the heat flux into the LH tank increases by approximately 20%. When the vacuum rises from 10 Pa to 100 Pa, the combination of VCS and HGMs reduces the heat flux into the tank by 58.08%–69.84% compared with pure HGMs.

关键词： liquid hydrogen storage     hollow glass microspheres (HGMs)     self-evaporation vapor-cooled shield (VCS)     thermodynamic optimization    

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Formation of CaCO hollow microspheres in carbonated distiller waste from Solvay soda ash plants

《化学科学与工程前沿（英文）》   页码 1659-1671 doi: 10.1007/s11705-022-2173-z

摘要： For decades, distiller waste and CO2 were not the first choice for production of high valued products. Here, CaCO3 hollow microspheres, a high-value product was synthesized from such a reaction system. The synthetic methods, the formation mechanism and operational cost were discussed. When 2.5 L·min–1·L–1 CO2 was flowed into distiller waste (pH = 11.4), spheres with 4–13 μm diameters and about 2 μm shell thickness were obtained. It is found that there is a transformation of CaCO3 particles from solid-cubic nuclei to hollow spheres. Firstly, the Ca(OH)2 in the distiller waste stimulated the nucleation of calcite with a non-template effect and further maintained the calcite form and prevented the formation of vaterite. Therefore, in absence of auxiliaries, the formation of hollow structures mainly depended on the growth and aging of CaCO3. Studies on the crystal morphology and its changes during the growth process point to the inside–out Ostwald effect in the formation of hollow spheres. Change in chemical properties of the bulk solution caused changes in interfacial tension and interfacial energy, which promoted the morphological transformation of CaCO3 particles from cubic calcite to spherical clusters. Finally, the flow process for absorption of CO2 by distiller waste was designed and found profitable.

关键词： distiller waste     CO2     hollow microsphere     CaCO3     Ca(OH)2     inside−out Ostwald effect    

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Preparation of P

Wenjiang LI, Fei XIE, Dongxu HUA, Chunli ZHANG, Chen DAI, Zhenyun YU, Meizhou QI, Shaojun YU

《化学科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 314-317 doi: 10.1007/s11705-010-0573-y

摘要： Silica hollow microspheres containing phosphorous have been prepared by a sol-gel/emulsion method which uses tetraethoxysilane (TEOS) as the precursor for the SiO and phosphoric acid (H PO ) as the precursor for P O . The hollow structure forms an emulsion system which is composed of an oil phase (kerosene, sorbitan monooleate (Span 80)) and an aqueous phase (a viscous sol solution of ethanol, TEOS and H PO ). Some of the phosphorous remains in the final silica shell structure even after calcination at 650°C. The hollow structure of the P O -SiO (silicophosphate) was characterized by X-ray diffraction (XRD), polarized optical microscopy (POM), scanning electron microscopy (SEM), nitrogen adsorption measurement and Fourier transform infrared spectroscopy (FTIR).

关键词： P2O5-SiO2     hollow microspheres     sol-gel/emulsion     phosphoric acid    

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Protein microspheres for pulmonary drug delivery

Yongda SUN,

《化学科学与工程前沿（英文）》 2010年 第4卷 第1期   页码 82-86 doi: 10.1007/s11705-009-0307-1

摘要： A new supercritical fluid (SCF) technique was developed for the preparation of microspheres for pulmonary drug delivery (PDD). This technique, based on the anti-solvent process, has incorporated advanced engineering design features to enable improved control of the particle formation process. Human recombinant insulin (HRI) was used as a model compound to evaluate the efficiency of this SCF process. An aqueous solution of HRI with a co-solvent was sprayed into high pressure carbon dioxide that extracted the solvent and water, leading to a dry fine powder with good particle size distribution and near ideal morphology for pulmonary drug delivery.

关键词： advanced engineering     improved     pressure     aqueous     technique    

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Nanostructured hollow spheres of hydroxyapatite: preparation and potential application in drug delivery

Xiaojing ZHANG, Weixin ZHANG, Zeheng YANG, Zhao ZHANG

《化学科学与工程前沿（英文）》 2012年 第6卷 第3期   页码 246-252 doi: 10.1007/s11705-012-1299-9

摘要： A solvothermal method has been successfully used to prepare nanostructured hydroxyapatite (HA) hollow spheres with average diameters of about 500 nm and shell thicknesses of about 100 nm in a glycerin/water mixed solvent. Transmission electron microscopy (TEM) and field-emission scanning electron microscopy (FESEM) images show that the shells of the HA hollow spheres are actually composed of nanosheets with thicknesses of about 10 nm. By tuning the glycerin/water volume ratio, two other kinds of HA solid spheres with average diameters of about 6 or 20 μm were assembled from nanoflakes. The properties of the different kinds of spheres as drug delivery carriers were evaluated. Ibuprofen (IBU) was chosen as the model drug to load into the HA samples. The nanostructured HA samples showed a slow and sustained release of IBU. The HA hollow spheres exhibited a higher drug loading capacity and more favorable release properties than the HA solid spheres and thus are very promising for controlled drug release applications.

关键词： hydroxyapatite     hollow spheres     synthesis     drug release    

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Seismic performance of precast hollow bridge piers with different construction details

Zhiqiang WANG,Jiping GE,Hongyi WEI

《结构与土木工程前沿（英文）》 2014年 第8卷 第4期   页码 399-413 doi: 10.1007/s11709-014-0273-7

摘要： Currently the design scheme of precast hollow concrete bridge piers will be adopted in bridge design in China, but there is no code including specific design details of precast segmental piers in high seismic risk area. For comparative study of seismic performance of the hollow bridge piers which had different design details, six specimens of hollow section bridge pier were designed and tested. The specimens consist of the monolithic cast-in-place concrete bridge pier, precast segmental prestressed pier with cast-in-place joint and precast segmental concrete bridge pier with dry joints. Results show that all specimens have good displacement capacity. The bridge pier with bonded prestressed strands exhibits better energy dissipation capacity and higher strength. The un-bonded prestressed strand bridge pier displays less residual plastic displacement and energy dissipation capacity. The bridge pier with both bonded prestressed strands at the edge of the section and un-bonded in the center of the section not only exhibits more ductility capacity and less residual plastic displacement, but also shows better energy dissipation capacity. Compared with experimental results of prestressed bridge columns, analytical result demonstrates the developed numerical analysis model would provide the reasonable and accurate results.

关键词： hollow pier     seismic performance     cyclic load     precast concrete     bridge columns    

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Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

《能源前沿（英文）》 2008年 第2卷 第3期   页码 273-278 doi: 10.1007/s11708-008-0048-8

摘要： To have a good understanding of the formation of homogenous mixture in a porous medium engine, the interaction between hollow cone spray and hot porous medium was studied numerically by using an improved version of KIVA-3V code. The improved KIVA-3V code is incorporated with an impingement model, heat transfer model and linearized instability sheet atomization (LISA) model to simulate the hollow cone spray. The reasonability of the impingement model and heat transfer model was validated. With a simple model to describe the structure of the porous medium, the interaction between hollow cone spray and hot porous medium was simulated under different ambient pressures and spray cone angles. Computational results show that the fuel spray could be divided into smaller ones, which provides conditions for the quick evaporation of fuel droplets and the mixing of fuel vapor with air. Differences in ambient pressure and spray cone angle affect the distribution of droplets in the porous medium.

关键词： improved version     simple     impingement     atomization     hollow    

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Recent research and development of PLGA/PLA microspheres/nanoparticles: A review in scientific and industrial

Feng Qi, Jie Wu, Hao Li, Guanghui Ma

《化学科学与工程前沿（英文）》 2019年 第13卷 第1期   页码 14-27 doi: 10.1007/s11705-018-1729-4

摘要： Poly(D,L-lactic-co-glycolic acid) (PLGA)/poly(lactic acid) (PLA) microspheres/nanoparticles are one of the most successful drug delivery systems (DDS) in lab and clinic. Because of good biocompatibility and biodegradability, they can be used in various areas, such as long-term release system, vaccine adjuvant, tissue engineering, etc. There have been 15 products available on the US market, but the system still has many problems during development and manufacturing, such as wide size distribution, drug stability issues, and so on. Recently, many new and modified methods have been developed to overcome the above problems. Some of the methods are easy to scale up, and have been available on the market to achieve pilot scale or even industrial production scale. Furthermore, the relevant FDA guidance on the DDS is still incomplete, especially for abbreviated new drug application. In this review, we present some recent achievement of the PLGA/PLA microspheres/nanoparticles, and discuss some promising manufacturing methods. Finally, we focus on the current FDA guidance on the DDS. The review provides an overview on the development of the system in pharmaceutical industry.

关键词： PLGA     microspheres     drug delivery system     stability     manufacturing    

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An investigation into the properties of ternary and binary cement pastes containing glass powder

Marcelo Frota BAZHUNI, Mahsa KAMALI, Ali GHAHREMANINEZHAD

《结构与土木工程前沿（英文）》 2019年 第13卷 第3期   页码 741-750 doi: 10.1007/s11709-018-0511-5

摘要： The properties of binary and ternary cement pastes containing glass powder (GP) were examined. Hydration at early age was evaluated using semi-adiabatic calorimetry and at late ages using non-evaporable water content and thermogravimetric analysis. The transport characteristic was assessed by measuring electrical resistivity. The binary paste with slag showed the highest hydration activity compared to the binary pastes with GP and fly ash (FA). The results indicated that the pozzolanic behavior of the binary paste with GP was less than that of the binary pastes with slag or FA at late ages. An increase in the electrical resistivity and compressive strength of the binary paste with GP compared to other modified pastes at late ages was observed. It was shown that GP tends to increase the drying shrinkage of the pastes. Ternary pastes containing GP did not exhibit synergistic enhancements compared to the respective binary pastes.

关键词： cement paste     glass powder     pozzolanic reaction     supplementary cementitious material    

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Preparation and characterization of EVAL hollow fiber membrane adsorbents filled with cation exchange

Fengli ZHANG, Yuzhong ZHANG, Hong LI, Guangfen LI,

《化学科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 462-467 doi: 10.1007/s11705-009-0011-1

摘要： EVAL hollow fiber membrane adsorbents filled with powder D061-type cation exchange resin were prepared through dry-wet spinning process, using hydrophilic copolymer EVAL as the fiber substrate. The microstructures of the membrane adsorbents were observed, and the pure water fluxes, BSA rejection, and static adsorption capacities of membrane adsorbents for BSA were measured. The effect of the resin-filled content on membrane performance has been discussed. The results showed that EVAL hollow fiber membrane adsorbents filled with D061-type cation exchange resins had good adsorption capacity, and the adsorption capacity increased with the quantity of the resin-filled content. The static protein adsorption capacity was 77.14 mg BSA/g membrane adsorbents when D061 resin loading content was 65% at pH 4.5.

关键词： substrate     copolymer EVAL     exchange     EVAL hollow     resin-filled content    

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Facile preparation of polybenzoxazine-based carbon microspheres with nitrogen functionalities: Effects

Uthen Thubsuang, Suphawadee Chotirut, Apisit Thongnok, Archw Promraksa, Mudtorlep Nisoa, Nicharat Manmuanpom, Sujitra Wongkasemjit, Thanyalak Chaisuwan

《化学科学与工程前沿（英文）》 2020年 第14卷 第6期   页码 1072-1086 doi: 10.1007/s11705-019-1899-8

摘要： In this study, polybenzoxazine (PBZ)-based carbon microspheres were prepared via a facile method using a mixture of formaldehyde (F) and dimethylformamide (DMF) as the solvent. The PBZ microspheres were successfully obtained at the F/DMF weight ratios of 0.4 and 0.6. These microspheres exhibited high nitrogen contents after carbonization. The microstructures of all the samples showed an amorphous phase and a partial graphitic phase. The porous carbon with the F/DMF ratio of 0.4 showed significantly higher specific capacitance (275.1 F g ) than the reference carbon (198.9 F g ) at 0.05 A g . This can be attributed to the synergistic electrical double-layer capacitor and pseudo-capacitor behaviors of the porous carbon with the F/DMF ratio of 0.4. The presence of nitrogen/oxygen functionalities induced pseudo-capacitance in the microspheres, and hence increased their total specific capacitance. After activation with CO , the specific surface area of the carbon microspheres with the F/DMF ratio of 0.4 increased from 349 to 859 m g and the specific capacitance increased to 424.7 F g . This value is approximately two times higher than that of the reference carbon. The results indicated that the F/DMF ratio of 0.4 was suitable for preparing carbon microspheres with good supercapacitive performance. The nitrogen/oxygen functionalities and high specific surface area of the microspheres were responsible for their high capacitance.

关键词： PBZ     carbon     porous materials     microsphere     supercapacitor    

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Precision glass molding: Toward an optimal fabrication of optical lenses

Liangchi ZHANG,Weidong LIU

《机械工程前沿（英文）》 2017年 第12卷 第1期   页码 3-17 doi: 10.1007/s11465-017-0408-3

摘要：

It is costly and time consuming to use machining processes, such as grinding, polishing and lapping, to produce optical glass lenses with complex features. Precision glass molding (PGM) has thus been developed to realize an efficient manufacture of such optical components in a single step. However, PGM faces various technical challenges. For example, a PGM process must be carried out within the super-cooled region of optical glass above its glass transition temperature, in which the material has an unstable non-equilibrium structure. Within a narrow window of allowable temperature variation, the glass viscosity can change from 105 to 1012 Pa·s due to the kinetic fragility of the super-cooled liquid. This makes a PGM process sensitive to its molding temperature. In addition, because of the structural relaxation in this temperature window, the atomic structure that governs the material properties is strongly dependent on time and thermal history. Such complexity often leads to residual stresses and shape distortion in a lens molded, causing unexpected changes in density and refractive index. This review will discuss some of the central issues in PGM processes and provide a method based on a manufacturing chain consideration from mold material selection, property and deformation characterization of optical glass to process optimization. The realization of such optimization is a necessary step for the Industry 4.0 of PGM.

关键词： precision glass molding     optical lens     constitutive modeling     optimization     manufacturing chain     Industry 4.0    

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Nonlinear analysis of pre-tensioned glass wall facade by stability function with initial imperfection

Siu-Lai CHAN, Yaopeng LIU, Andy LEE,

《结构与土木工程前沿（英文）》 2010年 第4卷 第3期   页码 376-382 doi: 10.1007/s11709-010-0086-2

摘要： Pre-tensioned high strength trusses using alloy steel bar are widely used as glass wall supporting systems because of the high degree of transparency. The breakage of glass panes in this type of system occurs occasionally, likely to be due to error in design and analysis in addition to other factors like glass impurity and stress concentration around opening in a spider system. Most design does not consider the flexibility of supports from finite stiffness of supporting steel or reinforced concrete beams. The resistance of lateral wind pressure of the system makes use of high tension force coupled with the large deflection effect, both of which are affected by many parameters not generally considered in conventional structures. In the design, one must therefore give a careful consideration on various effects, such as support settlement due to live loads and material creep, temperature change, pre-tension force, and wind pressure. It is not uncommon to see many similar glass wall systems fail in the wind load test chambers under a design wind speed. This paper presents a rigorous analysis and design of this type of structural systems used in a project in Hong Kong, China. The stability function with initial curvature is used in place of the cubic function, which is only accurate for linear analysis. The considerations and analysis techniques are believed to be of value to engineers involved in the design of the structural systems behaving nonlinearly.

关键词： tension system     glass wall     nonlinear analysis     pre-tensioning     second-order analysis    

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Progress of three-dimensional macroporous bioactive glass for bone regeneration

Lijun JI, Yunfeng SI, Ailing LI, Wenjun WANG, Dong QIU, Aiping ZHU

《化学科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 470-483 doi: 10.1007/s11705-012-1217-1

摘要： Bioactive glasses (BGs) are ideal materials for macroporous scaffolds due to their excellent osteoconductive, osteoinductive, biocompatible and biodegradable properties, and their high bone bonding rates. Macroporous scaffolds made from BGs are in high demand for bone regeneration because they can stimulate vascularized bone ingrowth and they enhance bonding between scaffolds and surrounding tissues. Engineering BG/biopolymers (BP) composites or hybrids may be a good way to prepare macroporous scaffolds with excellent properties. This paper summarizes the progress in the past few years in preparing three-dimensional macroporous BG and BG/BP scaffolds for bone regeneration. Since the brittleness of BGs is a major problem in developing macroporous scaffolds and this limits their use in load bearing applications, the mechanical properties of macroporous scaffolds are particularly emphasized in this review.

关键词： bioactive glass     biopolymer     bone regeneration     macroporous scaffolds     tissue engineering    

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Pd nano-catalyst supported on biowaste-derived porous nanofibrous carbon microspheres for efficient catalysis

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1289-1300 doi: 10.1007/s11705-023-2299-7

摘要： Environmental pollution caused by the presence of aromatic aldehydes and dyes in wastewater is a serious global concern. An effective strategy for the removal of these pollutants is their catalytic conversion, possibly to valuable compounds. Therefore, the design of efficient, stable and long-lifetime catalysts is a worthwhile research goal. Herein, we used nanofibrous carbon microspheres (NCM) derived from the carbohydrate chitin present in seafood waste, and characterized by interconnected nanofibrous networks and N/O-containing groups, as carriers for the manufacture of a highly dispersed, efficient and stable Pd nano-catalyst (mean diameter ca. 2.52 nm). Importantly, the carbonised chitin’s graphitized structure, defect presence and large surface area could promote the transport of electrons between NCM and Pd, thereby endowing NCM supported Pd catalyst with high catalytic activity. The NCM supported Pd catalyst was employed in the degradation of some representative dyes and the chemoselective hydrogenation of aromatic aldehydes; this species exhibited excellent catalytic activity and stability, as well as applicability to a broad range of aromatic aldehydes, suggesting its potential use in green industrial catalysis.

关键词： biowaste chitin     nanofibrous     palladium     nano-catalyst     catalysis    

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标题 作者 时间 类型 操作

A novel cryogenic insulation system of hollow glass microspheres and self-evaporation vapor-cooled shield

Jianpeng ZHENG, Liubiao CHEN, Ping WANG, Jingjie ZHANG, Junjie WANG, Yuan ZHOU

期刊论文

Formation of CaCO hollow microspheres in carbonated distiller waste from Solvay soda ash plants

期刊论文

Preparation of P

Wenjiang LI, Fei XIE, Dongxu HUA, Chunli ZHANG, Chen DAI, Zhenyun YU, Meizhou QI, Shaojun YU

期刊论文

Protein microspheres for pulmonary drug delivery

Yongda SUN,

期刊论文

Nanostructured hollow spheres of hydroxyapatite: preparation and potential application in drug delivery

Xiaojing ZHANG, Weixin ZHANG, Zeheng YANG, Zhao ZHANG

期刊论文

Seismic performance of precast hollow bridge piers with different construction details

Zhiqiang WANG,Jiping GE,Hongyi WEI

期刊论文

Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

期刊论文

Recent research and development of PLGA/PLA microspheres/nanoparticles: A review in scientific and industrial

Feng Qi, Jie Wu, Hao Li, Guanghui Ma

期刊论文

An investigation into the properties of ternary and binary cement pastes containing glass powder

Marcelo Frota BAZHUNI, Mahsa KAMALI, Ali GHAHREMANINEZHAD

期刊论文

Preparation and characterization of EVAL hollow fiber membrane adsorbents filled with cation exchange

Fengli ZHANG, Yuzhong ZHANG, Hong LI, Guangfen LI,

期刊论文

Facile preparation of polybenzoxazine-based carbon microspheres with nitrogen functionalities: Effects

Uthen Thubsuang, Suphawadee Chotirut, Apisit Thongnok, Archw Promraksa, Mudtorlep Nisoa, Nicharat Manmuanpom, Sujitra Wongkasemjit, Thanyalak Chaisuwan

期刊论文

Precision glass molding: Toward an optimal fabrication of optical lenses

Liangchi ZHANG,Weidong LIU

期刊论文

Nonlinear analysis of pre-tensioned glass wall facade by stability function with initial imperfection

Siu-Lai CHAN, Yaopeng LIU, Andy LEE,

期刊论文

Progress of three-dimensional macroporous bioactive glass for bone regeneration

Lijun JI, Yunfeng SI, Ailing LI, Wenjun WANG, Dong QIU, Aiping ZHU

期刊论文

Pd nano-catalyst supported on biowaste-derived porous nanofibrous carbon microspheres for efficient catalysis

期刊论文